Azu stands first, writes the vowel a, and carries the numeral 1. Its name is the Old Church Slavonic word for I, the first person pronoun, which is the plainest possible demonstration of a habit that runs through the whole set: Slavonic letter names are ordinary words of the language, where Greek and Hebrew letter names are opaque to their own speakers. A Byzantine reader could not say what alpha meant. A Slavonic reader knew exactly what azu meant, and so did every child learning to read from a primer.
That transparency shaped how the alphabet was taught and how it was named. The Slavonic word for the alphabet, azbuka, is built from the names of the first two letters, azu and buky, in exactly the way the Greek word alphabet is built from alpha and beta. The construction is a translation of the idea rather than a borrowing of the word, which is characteristic of the whole translating enterprise the script was made for.
On a manuscript page azu is one of the letters most often enlarged and decorated, because it opens so many liturgical formulas and because an initial is where a scribe puts ornament. Used as a number it takes a titlo, a horizontal stroke drawn above it, which is what tells a reader that the letter is standing for a quantity rather than a sound. As the numeral 1 it appears constantly in the numbering of psalms, chapters, quires and years.
It survives unchanged in every modern Cyrillic alphabet, in shape, in sound and in position. Few letters of the original set can be said to have come through the last eleven centuries so completely untouched.