Ca opens the palatal class, the second of the five, and the order of the classes is what places it there: the sequence runs from the back of the mouth forwards, and the hard palate is the next point after the soft one. It is voiceless and unaspirated, the plainest treatment, in the same relation to its class as ka is to the class before it.
English speakers hear the sound as the ch of church, and the single Latin letter c used to transliterate it invites exactly the wrong reading, since c in English is either a k or an s and never this. The Siddham letter has no such ambiguity, and neither does the Indian analysis, which classifies the sound by where it is made rather than by any resemblance to anything else.
The letter enters conjuncts freely, most visibly with the palatal nasal that closes its own class. In East Asian transcription it has a long history of being matched to whichever consonant the receiving language had nearest to it, which is one of the reasons the Siddham letters were studied there as sounds first and as shapes second: a scholar who wanted to know what a transcribed mantra had originally said needed the letter, not the approximation.
The class it heads is also where the pairing between consonants and vowels becomes visible, since the phoneticians group the vowels i and long i with the palatals on the ground that they are formed at the same place. The letter table and the vowel table are two halves of a single analysis, and this is one of the joins between them.